© Distribution of this video is restricted by its owner
Transcript ×
Auto highlight
Font-size
00:09 So sorry, sorry guys. And they fixed the, the zoom

00:16 And for the question three is both mechanisms for sulfur enrichment, include oils

00:24 explain the effect of the source li this classic to its sulfur enrichment.

00:33 the, the reason why I I it clearly that uh in this

00:39 I really want to explain to you understand why the car system versus this

00:46 system. The why is so will so rich system which the cabinet system

00:53 the Swiss classic system is not really . And we know that the,

01:00 some the the bacteria of the reduction occurring in both systems. And uh

01:09 it can be reduced and by the in the presence of organic matri in

01:17 systems. And the class six classic and the is reduced. The two

01:25 sulfide, hydrogen sulfide partially can be with the ions to form the pyrite

01:33 is the which is the because it depends on the depends on the depends

01:39 the concentration of iron concentration in the column and also in the cold water

01:46 the C class systems, there is the terri source input, which brings

01:54 amount of the irons in the in system as a result, the most

02:00 the hydrogen sulfide that will will be with form the paras. So,

02:07 and uh there, there's a very portion of the hydrogen sulfide that can

02:12 retained in the water column, which be incorporated to the organic matter resulting

02:20 the relatively lower concentration of the organic . In that is this classic

02:29 In contrast, in the carbon system different carb system and the iron concentration

02:35 is a lot. So the once hydrogen sulfide generic hydrogen sulfide can be

02:42 with the from the. But the is limitation is it still supply of

02:51 . So the the carbonate system, is why the result in the carbonate

02:56 , all the all have two car know, the the all the g

03:01 the bacteria, all those kind of ecosystems. But the the one gene

03:08 in the carbonate systems and the hydrogen that can be partially reactive is the

03:15 matter to form the organic reach So, and some of them reacted

03:21 the high rise. So that's why why you see that. Uh typically

03:27 see that more so than the this really good. But the the the

03:35 is not really interpretation is not really and the sediment contain type two organic

03:41 for significantly more more gas than the contain the type two, type three

03:47 it's actually that's a reverse. That be, that's the top three,

03:52 it. The organic matter is it we call the, the gas and

03:58 two called the oil, oil gas is good for the gas. So

04:04 sent, this sent that should be top two sediments are also in the

04:12 oil, then have three. this is uh some degree is a

04:18 but most time like top three, know, we talk about the oil

04:24 because the have very specific, very uh allergies, giving organisms in the

04:34 and which which we will be variable generate the heavier hydrocarbons, which c

04:42 carbon numbers. So it it's also the top three oil is that is

04:50 is actually contained a high content and also should be revered. Therefore,

05:00 that origin from cabinet are more so than the sediment. You know,

05:11 to see the accurate actually a AAA , when, when you get into

05:17 oil, once you get into the , the content, sulfur content in

05:22 oil from the fifth of this And uh the Communists is almost

05:31 The significant difference is very, really , really the the the very related

05:38 is in a more mature and immature oil. So that contain a much

05:45 sulfur content. Be the main reason because the, the the character character

05:52 actually uh in a common system. is the to the sour which the

05:59 fun. So this, this is , I think that that is the

06:05 I I say need to need to emphasize that about the key, key

06:12 , key mechanisms is not because of , because of the different type of

06:19 organic matter, type two, top , it's actually even the same type

06:23 the organ, top two character and the cabinet system versus the classic

06:31 That's, that's the cabinet system. because it's good for the organic sulfur

06:37 character formation. So that's a, the heritage, the heritage of the

06:44 sulfur in the organic matter car. uh the, when the organ similar

06:52 that the sulfur, higher sulfur oil the beginning, it's heavy, heavy

06:59 . And that is the, that, that is how,

07:03 how the, the that the sulfur cost in the, that's one of

07:10 , one of the mechanisms that because the rack li difference. So that

07:21 think that is one that, that that from answer is that the,

07:26 , the answer, you know, , I really found that that is

07:29 thing I need to just grab it you a little bit. And uh

07:34 the, for the, this I know that I didn't really clearly

07:37 said that about what is all oil graph is a process of observing

07:47 unique pieces that are found in It's that is some part is

07:53 It's what, what uh first thing all over uh graph is still a

07:59 C chrome but to use it for oil characterization. And uh the,

08:06 the, the method of what we is we, we put the oil

08:12 a solvent and that the all the dis orbit in the solvent chain.

08:17 we use CS two, you know two, that's carbon carbon sulfide.

08:24 reason why we use the CS two a much lower bowling point, the

08:30 point is about 45 degrees. So the, before the all the large

08:37 hydrocarbon become volatile and CS CS two solvent itself is have been evaporated.

08:45 that's not really interfered any kind of , any, any kind of

08:51 the last kind of picks when when when run the whole G C

08:57 . So the whole G C C still still is the gas back.

09:04 for the whole oil G C composition , then we can run, run

09:12 quantification and the identification on the Both. I think that's uh I

09:22 that is the key good 22 I found that that's the answer.

09:26 know, he, he didn't really do the type to type to

09:31 some, some, some as well not to. I try to explain

09:37 to and uh yeah, yeah, . So the first one and type

09:48 more commonly associated with it uh So uh you know, for the,

09:56 our system, yeah, we have rich system and we also have a

10:03 class which is so it doesn't You are, you are the what

10:08 of ocean? It really depends on , your supply of your, your

10:14 of the materials and also your depositional . There's two system. Both rich

10:23 is a system and that this class a rich, rich system. Both

10:29 be developed in a top two Yeah. But the is in a

10:35 rich system because the the iron content low in the water column also in

10:42 water below. So the gene, sulfide gene from bacteria. So actually

10:49 the no matter you are carbon, things happen. But the only difference

10:58 generate hundreds of the preservation of the way that the hydro generation

11:05 And for the carbon system system, think so far that it will be

11:11 the reactive to the organic matter Didn't reach that don't reach the

11:18 And uh the portion of you will reacted with the from the why the

11:25 did they put the the the the still available for the for the for

11:32 organic match for the sulfur reach the matter? Uh because uh because they

11:37 really low concentration of in the so a result, you have a higher

11:48 in the system. Oh So this a classic rich system, you,

11:54 still have bacteria reduction. That is equivalent to reducing. But so that

12:03 be very, very quickly consumed by pilots. Why that happens? Because

12:11 , you know, like if you on so they can be very

12:15 react to each other extension. So do not have too much available hydrogen

12:23 far in the water column and the water reactor in the organ market resulted

12:31 a low. So, yeah, a, that's, that's why I

12:40 , so or, and uh I'm going to shoot other things and other

12:53 all good in particular. You the I think the last two,

12:57 , I really want to let you that why the, why are

13:01 the the two time critical time moments you can read it from the burial

13:08 and they gave the reason and I that's you, you interpretation is

13:14 And also I ask you that, , that's about based on the barrier

13:19 and gave a specific formation and let to describe the sedimentary process, I

13:29 , I think that's all good and will stop share this one.

14:18 you know, this, uh last I put a, put a

14:22 it's in particular, you know, the question six on the question

14:27 And, uh I'm pretty sure I'm sure in the final exam, I

14:33 definitely not the same as same as , the, the, this,

14:37 , the, the this one, the same as this one, not

14:41 as this one but uh very very similar things which I will provided

14:46 the literature. And uh let you let you to apply your knowledge.

14:53 why I want to emphasize more about two. And uh yeah, for

15:01 one, you see that uh the , oil, the the those are

15:06 rock from this, from this same kind of church, same,

15:13 similar or same kind of chat I provided for in the final, I

15:17 to want to all the knowledge that learned from our system to to to

15:24 to to to your work in the . So the, you see that

15:30 , we have a petroleum elements of from the geological time. You

15:36 we, we, we have definition the petroleum and the petroleum elements.

15:41 have five petro soft rock rock, rock and the, and the the

15:49 seals. And uh also the process like a generation expulsion, migration,

15:58 all kinds of things. We, , we discussed the uh concept that

16:02 do that. Now it is, know, this, this is the

16:05 of the final product about the We want to definitely want to,

16:12 , to. So that's like this is actually developed really. So that

16:21 that is the rock. And if look at the red light actually develop

16:27 was and if you look at ra is developed at same time. And

16:34 the group, and uh I see you over it's actually the distribution and

16:44 the track information, half information is . It, it's actually, it's

16:51 very similar, very similar to your the, to the, to

17:01 the, the the 20 million extended very wide range and the indicated to

17:13 and our is actually developing field. means that is actually forms, forms

17:20 long period of time. And then have to look at the oil generation

17:27 to the oil generation, oil generation actually fast very which is 100 and

17:34 million years. And, and the until the, until what until the

17:42 minutes. So that the see the extortion eventually rather later than the because

17:54 early generation oil oil is you need meet the meet the absorption of the

18:02 . Yeah. So and that's why need more oil and that is 100

18:13 and the generation 100 30 100 730 years. Ok. And then you

18:25 the, that means that if you have available types and uh if you

18:31 have available trap, eventually your oil be trapped and, and it after

18:39 yeah, and then that available, available property that here and we do

18:46 a critical critical time here. That because the end of end of the

18:54 information, this is one of the important critical time. That means if

19:00 , if you, this is the of the and then you see at

19:06 time, what happens in your and that will be a critical,

19:13 not critical time. And then this is OK. This is another time

19:19 this the end of the explosion and the explosion. That means that anything

19:25 this, if anything happens, if have a problem happens before this,

19:31 period of time, that's all And after this period of time,

19:35 no oil. So if you this the almost they can say,

19:41 if this system is OK, after 10 minutes, 10 minutes, the

19:46 20 million years to now and those of time is not good for the

19:52 accumulation so that you can make this on this charge and not like

20:06 But like this kid you analysis that say that a OK. If,

20:12 the, let, let me, me see that if, if I

20:15 this one, if I move this to here and also those those two

20:22 and then you, your critical time is not here. I think that

20:28 , it really depends on your track . See here is the generation and

20:36 the end of oil generation is time is slightly slightly later than the

20:44 of oil and but is not But the the tap information is really

20:53 information is really this two are it's almost, that's true. That's

21:02 it's critical a second, critical And here is that there's no oil

21:11 , all expelled the about two million ago. So, anything,

21:18 if you see that you, if trust, suppose you have traps from

21:22 , from the family is good. there, it's good, but there's

21:28 chance for oil charge because oil explosion been ended at 10 million. So

21:40 , uh, you know, you , you learn, learn the issues

21:44 the OK, from here. Let, let us look at my

21:49 animals. So, OK. So been developed in the lower Jurassic.

21:55 great. And I have even much than in other, in other

22:04 You, you, this is all column in your mind. You,

22:08 your here so is here. much shallow. So and then you

22:19 also develop in the same time. and then, and then you,

22:27 oil generation, your oil generation is , oh your brother, you have

22:32 , you have a really good, , really good at that start from

22:39 years. That means that you, , you receive a significant amount of

22:46 rock as you are all and uh is not issue for this case.

22:55 then, and then the, the that the seal and open racks and

23:03 know that they all good and the trap, yes, they had a

23:08 and that's the, and then if look at the information, OK.

23:12 time is it is great because this before this develop, this kind

23:20 is the information that it, it the, the the time is just

23:25 , just a very good here once the the the red deposit and then

23:37 , then the end to the many that has been formed has been formed

23:47 the many years that before and then we look at our oil, oil

23:55 that, but that's all we have reached. And, uh, and

24:04 look at the path, the path from about 100 million years to and

24:14 look at and then you have there's a high possibility this track because

24:24 time, the timing is very If this truck supposed, if I

24:28 this truck here, the risk will high. This will be if I

24:36 the this part here, risk is as well. But that's travel from

24:43 early that he says, no, , no oil, these two cases

24:53 then the risk is very high. is very, why would it be

25:02 ? Yeah, it talk about at time, oil, oil generations back

25:13 100 130 years ago, many years , 50 years ago, this kid

25:23 because the track, the track forms or that was a good thing.

25:32 what that, that, that could , that could be, could be

25:37 . But, and then you need think about that. If you,

25:44 the, the here is actually all learn from the right from here and

25:52 you see that you have very, , the, the, the the

25:57 there and then very just the slightly of the reservoir forms at that time

26:04 the reservoir form transforms and uh you not really have a oil, the

26:11 . Not that is still, I that's, that's about it. Unless

26:19 have something. This is really This is really good because it's all

26:29 , all the time. It's massive or so that's a very good

26:40 that's the one thing I want to want to. When, when we

26:46 final exam, I, I cannot this one and that is not good

26:51 you as well. Yeah, we , I will test, it's actually

26:56 , test, test means that we to know how, how good you

27:01 . And then if I, if make something, if I make something

27:05 the, the the is all I select one from the reference, the

27:11 , the many, many of those of things available in, in

27:15 you don't need to, you don't to, to, to read those

27:19 . If you have some, you read some reference to this system and

27:24 you really need to know. You need to understand how you can read

27:35 . And uh another, another you know, this is the,

27:38 I ask you you say, I it is uh which, what I

27:42 you to support the Bill cox have rack. The real have a,

27:48 you read this one, you see when you see that this, this

27:51 the, this is called I have formation names here. It's uh like

27:58 one. And this one, this is actually, and actually this one

28:04 OK, this, this one here the, and this one is the

28:09 , middle. And then this this one is the real, that

28:15 the corresponding each other. So you, you read it, this

28:20 , if you want to read real real is actually uh that's,

28:30 that's the, let me, let put the, the, the,

28:33 , the, the, the app you, OK? The same app

28:36 your app about 100 million years ago , or about 15 million years

28:47 And then continuously, you see that line, this is the cancer in

28:58 position in the range of this about 20 it's about 18 million years

29:03 to 22 million years ago. the, the sediment reach is

29:09 And then from here, you see , the slower actually from here to

29:16 . And then you use that, use the formation name or use

29:20 you use the, the to define . So the is is slow.

29:32 . And then what we see is about two million or one million years

29:37 we have a significant increase of the each. So you, you

29:43 you can, based on those you can get, get the,

29:46 read, read like this about Well, so the the direction is

29:54 on the temperature, right, and temperature is operational to the gap.

30:02 why would we see the curve Don't, don't. So I think

30:12 not. Yeah. Yeah, that because the, because, you

30:17 we have different definition rate and uh , the the what our maturity is

30:25 depends on the two things, maturity , we call the some maturity.

30:30 depends on the 22 factors. One about another one is, yeah,

30:37 why the that's why, you if you have a relatively, relatively

30:42 temperature but you have a longer time then you choose it could be equivalent

30:49 that very, very short term. uh but the, the higher that

30:56 that why you see that they see range, the, the this the

31:00 range and the green range or red they are shaping, shaping is not

31:06 not really the black line or Yeah, that's all difference on the

31:12 , different and the difference of the and also also the,

31:21 the, the silicon ridge is that's a true, that's why I

31:38 then any other question because this two in our final, we, we

31:43 have this kind of things. We it, it is not the

31:47 not definitely not the same on this , but we will use knowledge,

31:51 knowledge what we have we learn from here. And then like all

32:04 is someone who has not is actually . So that's I know like if

32:16 look at the real, that's another . You know, when we,

32:21 we talk about it, we talk the, the, the and uh

32:27 oil generation, all kinds of things the gas generation we will talk

32:32 So that's why if I have a , I will say, OK,

32:35 on this uh based on this various history and uh this history is including

32:42 the rocks. Yeah, in the , including all those kind of the

32:47 formation rocks. Then the graph Photograph is the, and then you

32:53 , OK, what happened about the . OK. And uh to this

33:04 is called, is called, which 30 to the 2028. OK.

33:20 then there is uh uh from this to here and then from the,

33:27 14 million years old as a and everything, everything younger than that or

33:49 , every, every everything, everything the, to the it's about 30

33:59 and it actually they do not really the window yet that something. And

34:10 we, we have a, this , this is our, you

34:14 you know, for real is not and then if we look at,

34:18 know, for real. OK. OK. Go there. Let do

34:23 all in the Zumba. That's the that, that, that's, and

34:32 and then to the, to the than that, then the,

34:38 the, the, the whole all really into or for this one,

34:43 this one is that the older generation going to happen? Yeah, that's

34:57 those things. You cannot really hear , but you have an idea

35:05 that this, that this formation increase a very short period of time.

35:13 , then that, that really increase signs that suggest that sediment real

35:25 right? That was just like, , that's uh it's still the the

35:32 in the high and referring it action referring that you, your signature which

35:36 high. OK? That is actually is back to this point. See

35:55 I think that the over burden overburden uh that is something what, what

36:00 guess. So the rock this is uh we say, OK, so

36:10 after this one, I don't know happens here after I do not really

36:25 otherwise, otherwise all from here, this one. So you for this

36:33 of thing, this table is what can see that here. OK.

36:51 else? It's, this is very simple. It's some, I I

37:00 some of them is the OK. , and, and then we watch

37:20 the, all the, the, , the history, what we,

37:23 we, what we show is we not really show the app yet in

37:28 , in, in the outside. . And, uh, I don't

37:34 to make that too complicated to you I want to have a relatively,

37:39 easy, simple system and in the , if you really work on the

37:45 basis and that more than you will that on that because if you have

37:51 , if you have some and for people and for this period of

37:57 we have no, no, any of and then, but the other

38:05 of things is too complicated. those are the relatively, relatively

38:19 So and then you inhabited the things the, about those, those

38:32 33 still the concept was still right the show. So I, and

38:45 get so close to and then all here and OK, the additional cost

39:08 and uh no doubt all the pressure pressure and chance you have and

39:21 I gonna ask some of them and, and call that the abnormally

39:28 pressure. And then in order to that this is a kind of a

39:39 to concept to plot. OK, , OK, the reason, the

39:44 you have a higher pressure and the processing because that to the uh go

39:57 the, the pressure is amazing. the only three s are using the

40:08 . Hi. Yeah. So if want to buy the same on,

40:15 that, so we just give 33 . Yeah, but you, I

40:25 on that one, those two do affect even those, this not

40:33 So this is what we call Not a very that, no,

40:44 , no, already, not really to the AIS but better than to

40:57 . Yeah, I, I know you, you, you, you

41:04 thinking if you have a offshore, can watch a column and you

41:09 but the water column, it has pressure, the pressure will be lower

41:17 the ology itself. You need you need to cut that in a

41:37 . OK. This uh this concept reflections we we talk about, talk

41:43 a lot of this one and uh think this is a very important part

41:48 well. You need to, in , you definitely need to, to

41:53 the what, what means normal linear that there's a depth versus the original

42:01 that was suggested to us. And the the normal ones versus the normal

42:10 and all that tells us in particular in particular the the those those kind

42:16 the those kind of the the typical are not relate to the one and

42:26 need to, you need to you need, you need to explain

42:30 . And I because the like this very, very different but because of

42:44 it, use it. Yeah. That's a lot. If the normal

43:02 is actually very well, this, is about the intrusion the intrusion is

43:14 the, because, you know, the, the, the, you

43:18 a, you have a in, the formation that the effect effect,

43:29 only very few me above and below and is really high in that,

43:39 few meters range. Wow. I, all things, I think

43:58 the people that you have a, have a same, same kind of

44:09 or, you know, to, two, uh, which, which

44:15 blocks. Yeah, that's all the . What, what I think is

44:33 is the, that is one of things is that for the mature,

44:37 know, when, when the history you see the sediment different and then

44:43 sediment is different. Yeah, that's , yeah, this is very easy

44:58 understand, see that. And this is linear one and this one is

45:02 one but not really, really have same, I guess that that is

45:13 reflecting the and a couple of Why is it? Why? Oh

45:22 , those are so this one? , let, let me, let

45:27 check. This one have continuously, sent to. Yeah. And we

45:34 over there, I think. And line of that is very, very

45:48 when you think of the very very narrow version of reflection change what

45:56 tells us. Yeah, there's still sediment to reach the sediment to reach

46:07 faster here, much faster compared to of them. That's why we're not

46:14 not really see the increasing like this one, you know, we

46:26 , there's two real online and another is uh so, so that the

46:37 guys, this, this almost, , this uh on this side is

46:45 . The reason, the reason they different and also different, that's,

46:54 not good, that's not good enough go. It's actually maybe the good

47:00 is this one if you like, you have a, you know,

47:08 of your you have and then you , they do not really, really

47:20 uh all the of, of, , of the because we do have

47:25 people. The the the this is OK for the thermal gradients support support

48:00 formation thermal gradient. Uh We we, we check that the thermal

48:07 is is the heat flu divided by thermal conductivity. Yeah. Is he

48:15 by semiconducting secon activity is functional group no, no, no, the

48:25 its function of this knowledge because Suntone and they have this conductivity.

48:32 And uh that's functional and the heat heat blue. That is what

48:37 we learned the key point. What learned last week. It's uh it's

48:43 the you need to count the this so that's you see really depends you

48:54 think about that's really depends on your larger tectonic environment. Yeah, it's

49:00 really small things. Yeah. So you can see here is of

49:05 you have a similar is don't have different, it's uh yeah,

49:18 well up to that is that your, your, your sedimentary age

49:24 not have significant change. And uh bigger challenge for bridge instead of

49:34 but he, it's, it's for , for the base and given period

49:38 time. He is almost, that's , I think that's the key

49:45 The key key lessons of what I last week when they do. Do

49:52 have that one here? Yeah. look at this model, this model

50:01 that this is the that use the to Christ for this kind of concept

50:08 of instead of sickness of our best on, I do not really this

50:16 concept to introduce the normal and they about the 120 kilometers, those fences

50:27 uh for our sediment basin, many places, you know, five

50:31 , 10 kilometers our but still still about 10% of that. This is

50:40 that's why they call it the normal , thin ones and the ones that

50:48 how, how they they they they thinking about China. So this is

50:56 this concept, this this kind of . We we should, we should

51:00 that because this this this kind of clearly gives us a indication says if

51:06 really want to change your heat flow your base model, that means you

51:12 to have some evidence shows that your activities, everything is significant difference in

51:19 this age of can work can can to another age of rocks. Otherwise

51:27 your heat flow cannot really charge too . You need to have a

51:34 I I think this is very very important concept. And in this

51:40 , we not on the the heat , it depends depends on the depends

51:48 the heated conductivity and also some geothermal . And the gradient is a

51:55 I think Q we know that this of this kind of set, big

52:05 set. Yeah. OK. One the actual, let me see.

52:15 I have no I, so the know the your input is unusual for

52:25 the foil fielding North Sea, you there is volcano there in, in

52:32 . So you know that boy is follow this global pattern. How do

52:39 ? Yeah. Correct. Yeah, a good question. I said that

52:48 that means let me let me keep this one in mind. It

52:52 a very important concept for heat and that has to go back, go

52:58 here, go back to look at , this, this I don't know

53:06 big body of the, the this kind of in. And if

53:14 look at this, yeah, it's uh uh 50 page whatever. And

53:26 see that you, that you, the, the which so in the

53:35 , real abnormally high temperature don't affected here and the top and bottom of

53:46 very, it's still very narrow. I want to say that if you

53:52 have the significant volcanic in, in the, the area that the area

54:03 your, your, it's very narrow only the only the volcanic rock interacted

54:13 the, with the that range of this uh this kind of thing.

54:20 , yeah, I, I don't we will be significant kilometers at.

54:31 . It's, and then go to , go get into the best.

54:37 then this, this case, they really affected too much. If

54:46 if you put this one, let , let me, I don't know

54:50 you can quickly change, you change mind or make a another thing.

54:55 this is, this is vertically talk elementary nutrition. And even if,

55:06 , if I, you know, it in a map in a map

55:10 I suppose it's the area have rock in the base in one corner of

55:18 base. And uh how significant is , that one corner of the,

55:25 nutrition that one of the best will the, the center of the they

55:37 be small if you look at if you look at this,

55:42 this thickness and the only effect that very small of your interactive bras.

55:53 you cannot, it's even that you cannot really, that they not really

55:59 your pitch too much. What we here. We do not really affect

56:05 too much. No. Yes, , yes. What else? We

56:24 to share. OK. It's uh the equation and with Sarah and

56:33 this concept definitely will be definitely will in our final as well. And

56:39 reason why it, it is important because the, the, the the

56:50 similar to the oil which is and that we call the solid material.

57:03 . And uh that's the in the chemistry. When you think about

57:09 , what are, what are very concept is about that if we have

57:16 oil, the gas and just think just look at the the hydrogen carbon

57:24 atomic ratios for the gas is 42 the oil, which we use the

57:36 . So just look at that the , hydrogen medicine in the enrich the

57:47 . So it definitely definitely have to some uh some carbon will stay in

57:55 the as a as a which is that's that is that you understand that

58:03 , this kind of very simple, uh and then I say,

58:09 I come, yeah, OK. thing about that, that uh if

58:16 want to look at the rate of reaction, what happened is that the

58:25 of the change of the, of big, big time that that is

58:35 very important that yeah, that's a , very important a problem volume of

58:48 equal, equal to the, the volume change initially of the the

59:01 um and also the, and she which is great. So that is

59:19 , and, and uh once the proceeds chief in and the department,

59:49 see that the time the, and with that one there, and

60:01 this equation can be this way and the K of the energy and

60:15 but that's the, and here you that the activation energy that is

60:24 the energy to su supply the, break it down, break down the

60:30 carbon of the cat. So that's and then you, you, you

60:36 some linkage, linkage of the carbon to our organic type. They are

60:42 because different organic type, we have chemical composition. So that is uh

60:48 actually energy is related to our organic then which is, which is,

61:03 this is, this is how, important of this the the help us

61:11 understand the generation of the oil and from the. And uh that's definitely

61:20 want to, to know that I that's uh you know, I have

61:32 the most important is that what we ? Oh yeah. Another thing is

61:39 the original, it's very, very measurement for the history collaboration. And

61:48 that the rest of the rest of parameters, even the T MA still

61:53 as good as black direction if you have available data, which are and

62:01 you definitely try to use that data your thermal history. Uh kind

62:09 yeah, but when you do the you read the report of the rich

62:15 of Black, I already show a times about that time, the,

62:22 Excel Sheet or whatever. Since I the report is about, let's say

62:28 , each group of, you need at least 20 or 30 parts to

62:35 it. That's why, you and that's why, you know,

62:39 need to really find the microscope, identify, really clearly identify which one

62:46 work we have not really represent, the, the, the history of

62:56 rock of that, right? Because is before they transported to the

63:07 So they already already by the the summer evolution cannot be good for

63:16 for the and then, and then other things about other things about only

63:27 only which means that, that, is deposit or organ organic matter at

63:34 same time as a set, you what you call it that and can

63:43 used for the, this is this is a very important, very

63:48 slide out. And uh you need need to, to, to know

64:04 I think that's all that's all for , you know, first week,

64:09 week, the homework assignment is much . It's all builders try to

64:15 That concept is much, much easier the last week's assignment. Last week's

64:21 is uh it's the, in we have profile and the base modeling

64:28 the petroleum system. Those are things important. We try to uh try

64:34 use the knowledge which we learned from last two weeks to, to,

64:41 , to that, to this two . Yeah. Any, any

64:53 Yeah, go, go tell you more time. We definitely will in

65:00 final, it's not the same as one, but I will give you

65:05 , let you to let you to . And what is the critical

65:10 Why? And uh what the, each of the geological elements including,

65:19 know, when you say OK, is the Jurassic Jurassic, the,

65:27 , and look like this line is , the uh and the is and

65:41 the all open racks to rock and from lower that in the beginning of

65:51 pressure to, to the, to to, to present and the track

65:59 and, and the for to, that and, and yeah, that's

66:07 you can do that with all the time, 50 million years to not

66:18 any guess and the generation and for kind of those kind of things,

66:26 know, read, read all those . When you, you answer

66:30 when you answer the answer this slide uh we provide a different slide but

66:35 same kind of the concept, same, same thing here. This

66:45 the, this is the, the again actually know that the formation

66:52 uh those, those are the different geological, a different formation here.

67:00 uh this is a geological age. that's 7123444 all line up and then

67:12 see the curve and also about my , let me stop. Share this

68:08 . OK. And our class will cover the issues about the alteration.

68:17 know, we have an oil forms a but the various of of alteration

68:25 will destroy the oil quality. So I'm going to cover the cover because

68:31 is I think that this class will alteration of petroleum in. OK.

69:02 good. Yeah. And uh so oil was formed from the carro through

69:11 maturation and uh after accumulated in a and then that there will be various

69:20 processes can be out the oil quality is we call the alteration of petroleum

69:27 re so that and we know that , you know, we, we

69:35 about a lot of the sauce rack from today and tomorrow we will locate

69:42 oil itself and the petroleum characteristics can influenced by the numbers of factors.

69:51 know that organic type and source rocks affect the potential product composition. We

70:00 a took the lunch time to describe one and he is still some kind

70:07 the high level, the summarized we talk about them. And the

70:12 thing is that if we have a evaporate and including the gypsum Adra and

70:22 , and these are the inadequate source . If we, if we have

70:27 lower price and uh refresh, refresh indicate the slight refreshing of the water

70:40 and deposits the fine grade cabinet and are often the excellent source rocks.

70:49 we, we already show a lot times about the two very important parameters

70:59 effect a source rock evaluation. And mine is a which is organic

71:12 organic content. So it's, in words, if we should do the

71:16 rock characterization, abundance of organ matter is uh is one very important factor

71:27 is QC we talk about. And the second one is a total

71:34 potential off the rocks. So here see, you can see that high

71:43 uh I see the red red points actually have a lower and a lower

71:52 and the age on the mouth and on the very become very contains the

72:02 O C and the high uh generation . And we also uh divide the

72:13 become oil proof and the gas pro . And uh this is the summary

72:20 the cur. So we have a one, type two and type three

72:26 . And we use a different word the term called, called top one

72:31 a character. It's actually, you , that's a microscopy s characteristics show

72:41 offer and uh at car elemental That's uh so just that one contains

72:48 high hydrocarbon carbon ratios and uh also a high content which is uh deposed

73:00 marine and the Lucas shell, the and which have three is actually structurally

73:09 called a matter and uh chemically chemically composition content, the lower hydrogen carbon

73:19 , higher cell content and those are from the source. And uh they

73:29 have a mixed humi and gens which developing in the near and data

73:39 And those three kind of went through maturation, shut down oil that's from

73:47 one gen and oil and gas from two and the mainly gas from top

73:56 . So we know that gen types be characterized by three different methods.

74:04 is the morphology to use the organic graph. And another one is the

74:11 elemental composition, including carbon, atomic ratio and oxygen, carbon atomic

74:19 . And uh and the third which is a very useful one,

74:24 is a paralysis. So when when I talk about those three

74:30 I believe that you have a, have some plots in your mind.

74:35 . And uh those are the things , you need to to know that

74:42 for the morphologically classification of organic matter uh those are the results. And

74:51 you can see that the organic the the structures on the microscope is

75:00 different, know that have one knows that type two character knows that

75:05 three character. And also when you at the, the pyrosis which is

75:13 hydrogen index or oxygen index, once can see that shows up here.

75:20 uh and uh last week, I say that hydrogen index, oxygen index

75:28 rock rockery is it got a full parameters from Parader, which is S

75:37 S two S3 and the TMAX. uh and also, you know,

75:44 one and S two peak, we be separated even more the same,

75:51 more back use the PC. That what we, we did talk about

75:58 one last week. Those PC C don't need to know that one,

76:04 you definitely need to know the Is that what are four key parameters

76:12 for that? What each one represented and the index, oxygen index.

76:23 is the summary of the classification of and their depositional environments. And uh

76:31 have a current type one type two three and metal compositions which is the

76:38 pet graphic method. And uh the column is about hydrogen index which is

76:45 the rock paralysis and the the is is, which are and uh have

76:54 here and uh which is based on uh organic graphic environment of the rich

77:03 the indigenous indigenous of and uh also product which is generate the hydrocarbons,

77:13 we talk about the C 15, know, based on the C 15

77:18 and look at that and uh corresponding the depositional environments and that this is

77:25 very good summary table. And uh hope, yeah. So four

77:35 Yeah, top four is, we do not that too much because

77:40 four is uh see the top ratio in is less than 50. So

77:47 almost uh no oil on a cat but today actually exist in. So

77:57 why the table including the and in , in our whole whole lecture,

78:03 do not really talk too much about this table that is a little gas

78:11 if if and also of the hydrogen . And uh if you look at

78:17 metals that, that yeah, top do not pay too much attention.

78:26 top four have 123. That is , that's the, that's a very

78:31 things. And I want to know and have 123. It's the,

78:37 the they are characteristics, the reason that is important because the that is

78:47 to our oil compositions. And uh know, the top one collagen type

78:53 collagen is that and the bacteria dominant organisms, the pre precursor that is

79:01 living organisms that is dominated by the and the algae. So the as

79:06 result, the other result, see oil mainly composed by the car number

79:13 than 6 25. So it's but is that if you take the

79:20 three and then you have, so is the, that's the kind of

79:27 why we see the the importance of current type of effect to the oil

79:37 , you don't have, you don't to remember those things. This is

79:39 those those kind of any anything, like those ones that will help,

79:45 us to build a concept in our . And once we say,

79:49 type one, type two, type , those are the those those those

79:54 important because they are contained a different carbon atomic ratios, oxygen carbon atomic

80:04 , which can be the the use the can be similar or as a

80:12 of the hydrogen carbon atomic ratio and carbon ratio use the rocky hydrogen

80:19 oxygen index. And uh why they they are they are different under the

80:25 . Under the microscope, you can their structures, chemical structures are

80:30 Yeah. And uh why they are because it's uh because they originally originally

80:36 are living organisms in for form, the different kind of the the the

80:43 matter is different. So this is whole, this is the whole things

80:47 we want to to you bring bring together in your mind. So organic

80:52 up. OK. That's quickly you say oh that organ top carbon ratio

80:57 high and uh it's dominated by the and bacteria and under the microscope.

81:06 we can see the structures is mainly mainly composed by the that some

81:13 And uh I think that's that's good and it is oil proof and top

81:21 is OK. It's also oil probe it contains also higher hydrogen carbon

81:26 atomic ratios and the hydro higher hydrogen . And uh it's uh it's also

81:33 from the organism or living organisms is by the bacteria and the algae.

81:40 uh that's the, it's uh it's good for the oil and gas

81:46 and pa recursion is dominantly composed by some high plant materials. And uh

81:57 those, those ones have a con lower hydrogen carbon ratios and the lower

82:03 index is good for the gas And uh if you look at the

82:09 the microscope, organ ma is dominated the high plus mass groups, I

82:16 that's the, those those things, know, once, once we talk

82:19 top +123 and then those information is to your mind and uh that's good

82:27 you don't need to. And also that those things, those, those

82:33 all help to help you to, bring this concept together. OK.

82:45 , we talk about the, the already. So another thing is about

82:50 still some concepts. The, the why we, we emphasize this things

82:57 that's later on, you will see we will use these things in our

83:04 . And uh for the talks. the definition is that this is the

83:10 and the nu contain the same number protons, but different number of

83:19 So the po I use the, , this this kind of element basically

83:27 at the mask. And uh and I represented the mass number and

83:35 represented the atomic number. And for is the, the carbon, we

83:42 a no, no atomic ratio, number is six. And uh they

83:49 three different kinds of uh this one uh have a contain another six

83:59 So actually the actually the mass with 12, I think this uh this

84:09 the, it still, I think is still to belong to a definition

84:15 . And uh from a, you to know, you need to know

84:19 we talk about. The, what means is and what definition, you

84:23 , like if you can give, , give an example in your,

84:27 me one sec, hold on. then we have really three, it's

84:33 the, the, the three important the one is the problem. And

84:42 for the oil and the, for the oil and uh they use

84:51 not, I use the third, have a, you need to,

85:00 , you need to also know that this type of notation on there and

85:17 you got and uh for, for head that's actually in the, the

85:38 , the better to the I don't the avocado and then, and over

85:54 over 4 to 32 the standard. these are three different standards for

86:04 each of the, each of the . And uh those are the standards

86:13 like ocean water and the the the , the basic standard? OK.

86:23 , B to hydrogen. This is this is the standard for the C

86:28 to C 12 and this kind of four to second two. And uh

86:39 . I'm happy to hear to see those are the delta D all due

86:46 the delta H two by referring to here equals two heavier ones divided by

86:57 larger ones for the samples. The minus standard standard is this one and

87:05 by the standard of the numbers So the reason why the why is

87:13 because the variation the difference between the sample is and the standards and the

87:23 is small. So that is why use time. So to make this

87:29 of data notation number is bigger is easy for comparison. So the point

87:37 which I want to want to to know that is for the stable of

87:44 fundamentals that is OK. And you that, OK, if I use

87:57 OK, now hi please if I the carbon as an example, all

88:08 that to replace the replace the of carbon sounds like. So if I

88:16 this is for hydro and that not 100 and now I I want to

88:22 at a better for the for this it looks like can replace the hydrogen

88:35 , I I would see how, good they are very good. Do

88:41 do that to be real. Let me, let me just put

88:46 . So that time, yeah. the true on the table? See

88:58 the, the notation is the, heavier because the, the abundance of

89:04 heavier carbon carbon or b of any of things of the, the heavier

89:10 side, the abundance of that, is much lower than abundance of this

89:17 lattice. That's, that's, that's lot I know to the better

89:26 So that's equals two. So there's about a sea for the to the

90:05 557 seven. Um So that is the for the carbon. Hopefully it

90:21 me. And now I if I it to the sofa, can,

90:27 you if I change the sofa? this equation? OK. Cool and

90:49 . Yes. On Friday. Great. That, that is about

91:00 you say that it's actually if you this, this equation is a very

91:15 . Yeah, that's a, you that is that when we for

91:21 for the, for the, when marry the, as we marry the

91:27 , a mask abundance of the to abundance of the, that's that,

91:36 how we made ma ma and once measure this, it's no matter which

91:42 of sample, the maximum we measure carbon. So you buy see 12

91:55 that to the and then at the ratio compared to this gap is standard

92:05 and then it to get the figure how that reach in the samples compared

92:17 the so that this is how if I trans translated to that means

92:25 enrichment of the samples to be Oh me to the standard standard is

92:34 standard? And that, that, , that right. What do we

92:45 to come here with the standard? the same with this ocean water?

92:52 . Yeah. No, no, , no, no that's, that's

92:55 the carbon. Yeah, this the think this is the one we use

93:04 ratio. Yeah, that's a good know be because you know the the

93:13 have many layers. Yeah, we many layer layers. We have many

93:18 better than similar, similar level with same level. You made many many

93:22 from different. And uh what when , when you talk about when

93:28 when you talk about it, they OK, it's a carbon 13 is

93:33 0.1% and the current is about It can tell you this number.

93:45 will, you will feel difficult to . Yeah. And also difficult to

93:51 . And uh so it's actually, you married, you married, you

93:57 the abundance of the and abundance of black and uh you, you,

94:10 will remember that that that's kind of the the the the the numbers and

94:15 you report it, when you report , if you report that kind of

94:20 and uh the number is too no one really can understand it

94:28 it's very difficult to compare. So why, that that's why they come

94:35 . It's a kind of I have , everything you compare it to a

94:44 , that standard is fixed for the all the levels, no matter which

94:49 of level you have. The United in China. Look in the in

94:52 Europe, if you all use the kind of standard and better than your

95:01 to your standard. To think how you act of the, have you

95:11 of this international? So this is big, this is how the big

95:19 works, the communicator, you need have a communication language and the like

95:27 likely to be speaking speaking OK. if I first time come to

95:34 I say, OK, we he said, what are we talking

95:39 ? And then now after, after class to make three weeks of class

95:44 after the two weeks class and they , oh yeah, if I talk

95:51 OK, and that is a measure the extent of symmetry. If I

95:58 OK, you should have like 0.5 in our class. Yeah, you

96:04 like 0.5. OK. It's not the oil window yet. So the

96:09 not good. So you can make kind of communication. They are if

96:17 , if you say if you, you want to talk to buy

96:20 buy something, I will I will both richer. Oh, what did

96:28 read through that down? I do . You will use that. You

96:34 do that to them. Is that ? And, uh, the

96:45 the reason now we contract contract, know, you know, we don't

96:59 , ok, for the, we be very similar to what I talk

97:13 . Very, very, we talk , they talk about and we

97:22 we go 500 guests during the I know. And the you know

97:34 oil, oil. OK. Yeah, that right. Mhm And

97:53 for, for the, if I have I, how did

98:10 this is uh generation stage? Oh That, that, that all the

98:38 the only things you can tell is as a choice and I want to

98:47 a little bit of, little bit more knowledge for, for here.

98:54 uh if you look at the, at, look at the, the

98:58 binding in, in the process of start to assume the organic matter and

99:07 they will consume it very easily assuming push like eating the food,

99:14 some animals for eating the food. like the food. Yeah, because

99:23 , if I didn't turn on Yeah, that's, that's OK.

99:29 there's some, some delay, that's OK. So stage of the

99:36 organic matter react consumed by bacteria, consumed very easily, consume a portion

99:45 organs. In other words, in words, you know, we have

99:49 common bond in our organic PM that break down a very easy, very

99:56 about which is the container relatively. don't know about this because we know

100:06 carbon, carbon bonding determine the because massive smaller than 6 13, 13

100:16 that balance is easier to broke in the reaction. So as you reach

100:29 time, he reached and, and , that's true. Awesome. Look

100:46 the common and I will leave this and we will, we will answer

100:50 question to the my, how much the should the oil and gas

101:07 No. So that's also break down carbon bonds like that kind of a

101:19 , carbon 12, 12. And you put more energy than the carbon

101:27 £30 to be. So as you , oil, we do generate the

101:33 gas have a search because uh because down in the bacteria process and now

102:13 not that hot. We will have also have a to Yeah, in

102:26 , that that is it the the oil then oil is not some

102:47 . We heat the temperature deeper, , very organ deeper. OK.

102:56 to strike again. Yeah. And there is not after that because high

103:08 that you graduate easily broke down because get up. That's the order.

103:26 quite cheap. Have an and also that time you have a message you

103:36 any OK? We have three stages data values. And you see the

103:46 enrichment of the 13 enrichment of data will be increasing from the gas through

103:58 oil window to drag. You can that. Yeah. So as a

104:04 , what you can see that it have any use of the in the

104:10 , you will be look smaller will smaller than, than, than this

104:17 . Yeah, and this one will smaller than this one because the enrichment

104:23 the sensor is getting it is stronger to the and all the people,

104:43 number that time that that that a values in this. Bye. Uh

104:58 associate the gas fuel in the middle be a case that generation in the

105:07 , the after oil crashing. And you see that actually how that you

105:16 that we have and then you can that. Oh uh-huh uh-huh, the

105:46 awesome. That's the best location and the range of. Oh OK.

106:11 . Wow. Mm I'm not getting . That's when you read this.

106:27 , you get that point. Mhm is how that is about the uh

106:47 talk to differentiate different kind of OK the organic uh after organ position,

107:00 the organ symmetric on our so it's hopefully get this and I hope,

107:09 hope that's uh you know, my gradually easier for you to, to

107:16 as a as chemistry is a for I I my whole career to

107:29 to work on this those. Uh oh, that's a good,

107:42 point is that we, we look that data values, you know,

107:51 called the, and that's, that's enrichment of the healthier in your

108:17 That's why, that's why, you , I, I, I hear

108:20 use enrichment for enrichment. So the English word is used for the our

108:45 of a system. So this, two kind of words, it's actually

108:49 all related to that data, that definition. Yeah, it's that is

108:57 what what you see here. It's you, you can definitely I think

109:05 the because when you look at the I originally Yeah. Alright, bye

109:27 to your pre what? Yeah. maybe is more, more meaning more

109:38 . So this process, you see this is the whole in order to

109:42 all this kind of the processes is that's only the one the process of

109:47 we are talking about. The the generation of the chemical reactions doesn't

109:54 increase that against the they are hydrogen trope will follow the same kind

110:05 as the carbon is the reason is you know, those are the co

110:11 are the all follow the chemical reactions uh the through the through the increase

110:19 the concrete, we have a significant conversion of your precursor to your product

110:28 all from your car to the oil gas. So this process is that

110:33 actually that's in the, uh, call, the con is controlled by

110:39 , the temperature dependent the reaction process , uh, uh, that this

110:45 will cause cause the astro fractionation we the. And that's a, it's

110:55 little bit more, that will be deeper, deeper, deeper part that

111:00 , the, the point, the of which I want to, to

111:04 you here. Just let you know . Why. Yes, that's

111:22 that's all me, all me guess chemistry natural gas. OK. That's

112:00 . And uh you know, this two concepts you, you need

112:03 know because the tops introduce the tops uh a little bit deeper. But

112:09 I'm not really ask you too much remember all these kind of kinetic fluctuations

112:14 is too much. But you need know, you need to know the

112:17 the definition of a tops and in as top geochemistry, we use the

112:23 , not what that data notation equation what that means. It relatively enrichment

112:32 heavier heart a to the standards, standards, the notation after this.

112:42 uh OK. This is uh this just to give you an example about

112:48 , carbon. Top three. that's a, that's a heavy,

112:56 brick. We, we have um materials this afternoon. And uh I

113:06 it's the, the, you just me about the, you know,

113:11 the, the for the many geologist chemist they're working on the geological data

113:18 the geological time and those kind of and they use the, use the

113:25 carbon and the carbon 14 is it's used, used for the environmental

113:32 a lot because, uh, because half life time for the carbon

113:37 much shorter, three years, I think it's 5000 years.

113:44 it's about 500 years. 14. used a lot for the, I

113:51 . Hm. Yeah, for the . And also for the, for

113:57 people who, who do the, , do the, do the research

114:01 the. Yeah, I called the pad stuff. You know, some

114:06 is that they, they use the to a few 1000 years ago.

114:10 people buried and, uh, they their bomb and then, then

114:15 the, the, they get some piece of that they are bone

114:19 whatever stuff and even the hair and they can take the management of the

114:25 tops of the carbon 14 because the 14 content abundance will be decay,

114:31 , decay with the, and then can determine the, the, what's

114:37 age of that kind of the, , the, the place 5000 years

114:44 considered small is small. Yeah. love is his love but he is

114:53 . Ok. Ok. Ok. is a, that is relatively

115:00 And, uh, you see that is the, this is third time

115:05 . It's good. This is the part. I, I,

115:14 you see the why data because that the the the change, that's

115:20 small, very small change, you it actually change it only one that's

115:28 999. And uh and then if look at the ratio for that,

115:32 only minus one change. Yeah. what that's why the it's very

115:40 very small change if you, if say ok, 999 and the

115:45 if, if I report that 1999.2 you cannot really, really stupid,

115:53 don't know, 989, if you those things too much and people can

116:00 follow to follow the and if you , OK, by the small commute

116:08 to that, that means you only a one differences, the,

116:15 the of the and then if they to that, go to that,

116:23 to say OK, here's about here the that uh that uh it's about

116:33 the differences we talk about all those of very small, very small

116:43 So that is that I think this makes the, the, this last

116:48 , maybe, maybe help, help understand this, the del notation as

116:53 . And uh yeah, they, already show this one a different type

116:58 the source is actually formed, the , different uh all the composition of

117:06 oil that just shows how the C plus carbon distribution in, in

117:13 this is the of the oil and marine source, you see the vocabulary

117:21 the components, there's a two fewer two pi one here, those

117:28 those are called OK. You see , so that's the, the the

117:38 if I talk about this one, will become a say OK, familiar

117:42 know that I know that what data value is I say yeah,

117:49 This is the, you know that referring the different uh normal compounds contain

118:01 different yeah, number 13. So that individual, each individual and then

118:15 measure the aspect of the which which is the right one. Um

118:30 from the number of people on I know I'm not almost come to

118:44 the differences, the other one other this time, this time number 13

118:53 13. And so it's just just the same and then look at this

119:08 , this is another one. But can see that is you increase your

119:14 , your cover is actually increasing, and uh actually maybe suggest that they

119:22 not mixing cause. So you, can see that you consider that this

119:30 a, this is some of samples the river and the is about less

119:39 9 26 and this one is the minus 20. So that different

119:49 different samples can do have different carbon sign signature. So that is

119:59 that is the, I think that a very important concept of tomorrow.

120:04 will use it and uh to, , to refer it. So

120:09 that is like for natural gas, just show that for natural gas.

120:13 you have a natural gas, it's, that's all composed by

120:19 How do you know that, that medicine is sourced from the biogenic

120:24 , less than all the generator from oil or me gene in the

120:32 Or do you know that the only you can do that is to measure

120:37 ass and then trace back and once that number, if you understand the

120:44 , then you OK, you management 70 per so oh we minus 70

120:52 . That's a guess because why you make that statement quick because there is

120:58 people already do the many kind of studies and uh identify that minus 70

121:07 less than minus 65 that is in so that once you, once you

121:15 that kind of, then you refer and same thing here if you have

121:20 accumulating in red and how do you that the oil is sourced from top

121:26 Carro or top two Carro or rich this system or all the classic,

121:35 it with all the, you need measure that you need to measure the

121:44 of the parameters of the or and trace it back to the, the

121:52 . So particle I is one of one of the important things and uh

122:02 another another to today, right? and I this one actually this this

122:26 to natural, it also have a , those are the things, those

122:31 the things, things that to, get the best, the the people

122:37 really work, work, work, on uh Joe workers working in the

122:42 . You need to, you need build all this kind of uh key

122:47 and model and say, OK, gene from top two characters and what

122:53 typical character. And then you need build up this kind of the the

122:59 be called the references, once you up this references and then say,

123:05 , my best produce all like You only have one sample from all

123:10 samples. How you can make story samples, how you can make

123:17 I do the wrong my I had , my company through the wrong success

123:21 little bit. Produce about uh you , 1000 barrels a day and in

123:28 and you, you make some say, OK, this is

123:33 how you come from and what you and what kind of are all kind

123:40 how you can do that. And you need to build up, you

123:44 to build up this kind of and this kind of phase, that kind

123:50 that kind of very, very or uh also, you know,

123:59 very, very different uh different secondary process in the build up this kind

124:06 uh reference. Once you have this build up and then put your oil

124:12 analysis and what, what the, the things they were doing and then

124:18 all the samples in the reference you know, different plots and then

124:24 have some ideas. So the, that that is how, how you

124:30 , how you can provide useful information your company and that your company realize

124:36 you are very useful. OK. uh for the rock for from the

124:49 topic, uh the, the, , this the, the, the

124:52 slides that talk about the set so can be formed from the, the

125:00 , reach the close and uh and ring reach the cause can be.

125:07 you said that, I think that said that we know that three which

125:13 a structures, yeah, is a character and some bass, they found

125:20 con sets condensate accumulation that is, is actually related to the core.

125:28 why they, that's why they, they are still the rich. And

125:38 there could be some degree of oil the at high completion or could it

125:43 space separation cause the and uh uh in the center accumulation and the impact

125:54 the disability of P S and the product, the product, crude oil

126:00 . And uh there can be uh heavy oil that can be a sulfur

126:06 , enrich the oil. And uh there, there are some uh some

126:12 source reduction in the oil reservoir, I the focusing few, few

126:21 And we already talked about this line this line is actually we, we

126:27 in our homework. We, we just let you know that how

126:31 different uh system, carbon rich system the system, the sour content in

126:40 oil will be different. And uh is a, this is a,

126:47 that I can see that that's at beginning, we have all the organ

126:55 usually have a he calls over the in the water column and in the

127:04 water, both of that. Um uh and that's that. And if

127:33 go to the carbon rich system and still, you know, through the

127:37 reduction, you form the hydro and part is the, the form and

127:47 still have a valuable hydrogen sulfide react the form that organ can reach

127:54 reach the car and I that have a high and if they continue the

128:03 of increased temperature and form the high if the further increased temperature sub,

128:10 know, see that high oil, crude oil, it can be also

128:16 be become low sulfur oil, the in the increase of the, the

128:22 because the hydrogen sulfide can be quickly from high over cut. I have

128:30 to read to their lower package. this is the how is this

128:35 This is actually this is so petroleum are influenced the mostly profoundly by alteration

128:56 the petroleum within the reservoir. In words, you know, it's the

129:00 generated from source rocks that is oil de determined by the current types,

129:07 by the maturity. Once they charge inter there are some alteration processes

129:19 And uh I try to look at alteration processes in the reservoir.

129:24 This slide, I I really want pay more attention about this slide.

129:28 is the the how how you can the alteration process is alteration for

129:35 We have a carbon and a classic continental all marine system. Those are

129:45 sauce. This is, those are sauce and then generate the oil after

129:53 accumulated in the you in a re know what happens, OK? That's

130:01 in the water of the water. of course, I I I did

130:10 one time as what was it can the oil and watch a contact

130:17 If the you know the oil and surface is like this. If you

130:23 a type of additional charging and then say additional water comes in and cause

130:28 oil water comes to service like Yeah, that's the water and then

130:35 degradation because the water will bring some to the river and will cause the

130:44 some portion of the oil and cause cause the oil to bad degradation at

130:51 side. That's a exit the I'm sorry. Look at this.

131:01 you, you can go to a and uh the form can perform the

131:09 gas actually to say, OK, the oil for the the and also

131:20 uh gene generation more gas. And got another process actually, the area

131:32 process if the maturation process mo mo the increase of the called the called

131:42 called the auto charge. And uh thing thing is about the increase and

131:48 temperature in the reservoir and also can called called the red and the oil

131:57 the organic oil and oil can be oxide by age. So this is

132:06 this this this is this is the of the this this slide. And

132:14 so this is a very important I definitely want to know that and

132:18 know that I I always put put the the description questions for you

132:25 your homework assignment. This will be alteration after accumulation and uh by the

132:34 the bacteria alteration reaching the didn't really at a lower out. And then

132:42 was the water? Water is really on the solubility of the organic,

132:50 oil components in the water. We that some oil components like aromatics have

132:58 much higher solubility in the water compared a so that the difference in the

133:03 . So change change the composition and gas, which is uh called the

133:14 that secondary gas check is actually like from oil charge and sometimes indued aspect

133:27 . And the garlic is a dish referring to the the thermodynamic cur and

133:35 the reduction which are occurring at high and between the high carbon and the

133:47 the car eventually. Yes, which talking about a lot occurring at high

133:54 the also some stability, not stable then some. So those are the

134:04 or six alteration processes. We definitely to know this slide. And uh

134:14 also to see here is a further about the petroleum fire degradation. This

134:20 a very important process because the degradation the oil process in the stages.

134:26 uh this just shows the shows the of the oil, the the oil

134:34 to the original. So this is those are all this, this,

134:41 is the original oil without any bio . And uh I I like the

134:52 apple level. You can see that the whole apple and the whole without

135:02 operation and then the has a very and then you see the to the

135:19 the idea that more you see that this point, this point, those

135:27 that increases the the yeah, not be consumed by bacteria. Yeah,

135:55 uh like we have an apple apple and a little apple but then

136:01 they eating apples and then without in without the consume and the US is

136:13 still still there. This is all by the you see the, the

136:19 gravity become 29 it also increasing and still have a 70% saturation. And

136:29 you go to here, this is same at the beginning. It such

136:37 what you can see that is all almost you cannot. And uh what

136:47 here is the from 14 to So what that tells us is that

136:54 , this one is very good very to the high court normally.

137:01 this one become heavier, become The oil quality is that it changes

137:10 and uh this increase to significant, a 0.5. This is the 60

137:16 almost 100 times increase. Let me . Yeah, more than and

137:25 then the satu saturated hydrocarbons saturated carbons a 30%. You see that with

137:33 the degree of the degradation, the dramatically decrease representing the lower saturated

137:46 you know, there, you and uh further, yeah, we

137:54 this, this, this graph already what you can see that and the

138:00 all generation that are here and anything in the best and uh about about

138:13 the normal and then the and the uh and like this of the that

138:33 of and go to here got here the become 22. And uh c

138:43 system remains a very small portion of hydrocarbon is what you can see that

138:50 , this, this oil contains So the aroma is not good,

138:56 , good for the, the more to against. That's why, that's

139:07 they see the, the oil oil, oil quality change to imagine

139:12 . So when, when you drill well here as the original oil is

139:17 from over there. But, but the fact, I think this

139:28 we already did the show this one . I don't want to spend too

139:31 time for this one. And uh shows the different, this is

139:43 the oil and uh all that oil oil and go to the heavier

140:04 high and that we get the oil the hero when you normal car is

140:18 , this is another one that just the oh this is not the,

140:22 is the that or it's uh this not the old one is uh uh

140:36 , the oil and uh and the there for 32 days, they consume

140:46 kind of and this is for the , but there is still no more

141:03 for the and go to the, 44 days and they that so that's

141:18 natural level of observation compared to the , laboratory uh experimental bi degradation.

141:25 shows a very similar trends. those, those shows the process is

141:32 and uh original, very highly the . And this, this is the

141:45 original. And uh another another issue very interesting is that, so that

141:59 percentage of normal, the temperature and see that increasing, increasing of

142:08 the one smaller and smaller and the one and uh uh the, you

142:18 , your normal uh concentration curve, can get a really good corresponding to

142:24 sum shooting. And those shows the the oil gravity, the oil density

142:32 to the, correspond to the gas this, this area. And it

142:37 the uh so for the, the of the barrier depth and to and

142:46 , and the, and the increase the oil to be getting better.

142:55 is uh doesn't look at a comparison oil. You see, look at

143:07 , the diagram looks like different, uh proportional those and the saturate become

143:29 less. And uh as so, the no oil is actually only

143:47 This is one key study shows about in the north front of the Wilton

143:53 . And uh the oil variety, is that the oil gravity very

144:05 sad and uh all is increasing. if you look at content, that

144:15 another thing that content is that this I go towards this side is

144:24 And that is because of the, the increase of the summit increase of

144:30 chain, the sulfur, the oil less. Originally, originally, the

144:37 mature oil can be the 3% of sulfur. And once you reach the

144:44 off oil, the oil contribute will less than zero. And uh this

144:52 the shows some uh some concept to drawing about the uh type of those

145:03 of the and the, and uh line that should show the, the

145:29 . And because the black was is , the attack presentation and, but

145:38 the that is still that area still oil. Yeah, this graph,

145:47 spent some time to learn this graph actually look at this one that

145:59 Well, so that very deeply enough oil gas and everything I'm talking about

146:15 oil. It's, it's because that's pressure is high temperature is high

146:21 there's no separate gas, no all gas, all form the

146:30 the original original if this one and then cause the separation because the pressure

146:43 . So you have a and for get to the in the shadow shadow

146:50 and then you have the separation on , you have, you have this

146:57 of uh or separation process during the thing here, you, you directly

147:06 to have some and uh you could about the or something else and uh

147:16 separation. And then then for you can even more significant separation from

147:25 shadow from shadow. I think actually kind of technology that want to want

147:31 deliver from this slide. So this how the affect the, the uh

147:42 the oil for the on the gas . And uh this is the dash

147:48 after the 1.5 I I don't know 1.5 or two, that doesn't give

147:57 better idea that the, from the , the increasing of the and then

148:05 can see that clearly corresponding to a . This is, this is,

148:13 is very obvious in a, if go to a G I discover it

148:19 you before, from north to south the, the increase of bar

148:24 that's an unconventional play. And you a very clear separation of uh heavy

148:31 zone, normal oil zone to the condensate to the gas, to get

148:37 , very clear trend that qualify Yeah, this line is I

148:46 What is this for the oil? the was the and this is on

148:57 actually what you, what you is increase of the increase of the that

149:09 uh that, that, that that is, that is by

149:14 our and they, they have they have some publication about the ego

149:20 the, for the, the oil . I don't think you have time

149:25 read that one. I I hope have some time to show some of

149:29 result if I have time tomorrow. uh I think that's the the

149:42 Let let us have a very short and then I will get into the

149:48 of soft reduction. Yeah, let talk about another very important processes out

150:02 oil quality in nature. And uh is thermal chemical surface reduction. And

150:10 previously, we just show that on the body gradation affect oil quality that's

150:16 by the water of ocean. And bacteria of for this process is nothing

150:22 to bacteria is really related to the itself and also the heart temperature,

150:29 temperature. So this is the definition the T S R. The most

150:37 prominent a biogenic her biogenic alteration hot carbonate reservoir. That is the

150:45 of sulfate to sulfide coupled with the car carbons two carbon dioxide, which

150:55 determined as a thermo chemical action paid attention here and the whole thing about

151:08 process with nothing bacteria. And the thing is that is a in the

151:20 and uh and also including the in the reduction of the sulfide and the

151:28 of carbon to 202. So that can see that from the, the

151:36 the two products we are going to , one is about the hydrogen sulfide

151:43 another one is CO2 and uh and , and the hydrogen sulfide and CO2

151:50 become a big risk for the for oil, this kind of oil reservoir

151:57 and development. So that's, that back to 2000. Uh yeah,

152:04 back to 2000 above. And uh that time, shale oil and shale

152:10 is not really come to the play . And uh that many, many

152:19 and gas exploration go to the deeper and uh and and that, that's

152:29 that is including the, including the and onshore at that time. You

152:35 , it's the based on our based on our current regeneration model,

152:39 know, that is the oil can similar stable in the oil window.

152:45 , oil and the battery beyond the window. If the oil controlled by

152:50 thermal alter, that is the product be condensate unnatural gas. But when

153:00 people start to explode in a deeper hot carbon reservoirs, some

153:07 they found a very high concentration of hydrogen sulfide. And the CO2 that

153:14 you as you know that and the economics become a, become, become

153:18 lower, the risk become much So that is back, that is

153:23 2001. The people try to understand these processes are occurring. I that

153:30 that how I was involved in this study in a caltech. We try

153:37 look at the the key mechanisms to the this reaction in the sub subsurface

153:45 and how we can predict this this because once you can predict it and

153:51 you have a ability to avoid getting that area for your exploration activities.

154:01 also also if you really want you prepare for that say,

154:06 this will be going to be a hydrogen sulfide risk area and then you

154:13 for, for that and for your and for your product, the production

154:19 you need to remove the, remove hydrogen sulfide from your, from your

154:25 . And also hydrogen sulfide is toxic corrosive. And if you do not

154:32 treat well, they will cause issues safety issues. And uh there's a

154:42 general except T si reaction mechanism and you can do that is um look

154:51 , look at the, look at problem in the presence of the formation

155:03 form by the CO2. And you , and this, this reaction can

155:14 into two reactions which is with the and the, and there is

155:26 And so this is a very general of reaction and 2003. And uh

155:40 this means this means is that if you have a, if you

155:45 have, have the C I action and uh you need to reduce the

155:54 , which should have a proper balance six to the sulfur sofa, which

156:03 so minus two. So you see this is the, the,

156:08 the, the, the status is change from, from here to the

156:16 of the, it is the reaction this is a very clear, very

156:25 . I think we realize that and also the sulfate as we know that

156:32 the, in, in our we have the that developed, those

156:38 the main sulfate and uh your sausage to be dissolved in the, in

156:45 formation water to contribute to the, sausage ssl o uh the,

156:58 so, so I usually say, , maybe the soluble sulfate and

157:07 so those are the two factors control reaction. And uh also what we

157:17 here in order to take off this , you needed to the initial initial

157:25 sulfur species like so like a in to make the reaction go. So

157:33 is the statement, this is this is the, the, the

157:38 understanding, OK, This is the of we should get, they should

157:43 the show, the show, the the occurring in a and uh so

157:50 I just say that the because they the value of carbon resources because of

157:58 carbonation and will affect the the ratio result in a higher uh uh affect

158:09 and also affect the maximum depth of the oil occurs. We call the

158:15 data and as I said, hydrogen toxic of the of the corrosive and

158:24 can cause the, the the the can be corros. And in other

158:29 , you need to really, if really want to develop this, this

158:33 the deep of the oil and with higher to have a really a higher

158:39 pipeline good. And also also that need to remove the hydrogen sulfide before

158:48 , before you really sell, sell products to the, to the market

158:53 add the add additional cost to, remove the hydrogen sulfide. And uh

159:04 for the naturally the people over that that look at this, this

159:09 the scale of this six kilometers. uh what you can see that the

159:17 of what put it here, that the concentration of the hydrogen sulfide and

159:23 that concentration and so far in this is high and uh this is about

159:30 kilometers away, so six kilometers away then concentration become lower, it become

159:37 coin. So how how you can really can predict those things know that

159:45 that oil know that the oil do contain the hydrogen sulfide. No,

159:51 the oil field contain the low hydro that oil contain a high sulfur.

160:01 then the range here is it about over all from here to there is

160:07 than less than 20 to 30 kilometers . And the boundary between the high

160:13 the road, the hydrogen sulfide, oil, it is less than three

160:19 . So this this make the prediction very difficult. It clearly suggest that

160:27 suggest that the temperature is not only factor. So how you can have

160:32 really significant temperature change to cause this so that the temperature is not the

160:38 factor. So the if you make make the, we really cannot

160:44 really, really see that too much here to something else, which is

160:50 we talk about. And once you see that also the next one that

160:57 that now you can get you can you look at this, this part

161:01 say, oh yeah, I this is for me other content and the

161:14 which is the standard, the standard actually my phone either drink or the

161:53 site drink decreasing over the. So is this is this is very,

162:08 good observation that go go he is is. So this give you another

162:27 see that the is is useful and for us to make uh some

162:35 OK. And uh I don't want to remember these things, but I

162:41 I want you to understand this Yeah. And so this shows the

162:47 act of change of the oil and gas. OK. Is that means

162:53 organ uh all the organic or the in the water, OK? In

163:02 water and the with the sea water through the microbio sulfate reaction and the

163:17 to the to the generator product. , so high and organic.

163:24 so you can understand why this process taking place. Yeah, because bacteria

163:30 the reduction in A and A is ions from the and the so called

163:40 interaction reactivate the organic matter to form organic reach. So that is how

163:53 then then go to the go go the the further further you know,

163:59 water with some you know, you organic. So and then then you

164:07 the further in the in, in hot water. And uh still we

164:13 the can be went through the bi reduction and uh released some hydrogen release

164:23 CO2 and form some additional hydrogen So on the p one thing those

164:32 in the water column is occurring in water and the shadow sediment as

164:38 And as a result, as a will formula I for and I and

164:48 the early stage and the, the back and generate the sulfur

164:56 high sulfur country in the oil, is yeah. And then before

165:01 before they go to this station and action you will continue to, to

165:06 a lot of oil that immature oil release the happiness of. So let's

165:14 that, think about that during during the early oil generation and uh

165:20 sulfide is released arch from the high carro and uh as the sulfide and

165:28 oil is become a sulfur because the sulfide has been released. Hydrogen sulfur

165:34 been released as hydrogen sulfide. And for the, this this range is

165:44 if you have a involved in and have a more mature, involved in

165:53 car and generate the additional sulfide on sulfur that's through the thermo chemical production

166:01 much deeper. It's even beyond the of and from the look at

166:10 what, what's the result form that mature oil? That is a higher

166:16 sulfide and also comes with the higher in this oil actually because you generate

166:23 sulfide and the react reaction, the occurring here. But, but here

166:29 that with the oil and then increase sulfur content in the oil and even

166:35 , the, the all the high oil but still have a higher because

166:42 was because of this. Ok. one is just to look at the

166:59 the C 15 class groups type of for the T S R or the

167:08 from, from Alabama. And uh are the different fields and they indicate

167:14 different kind of the different kind of alteration of the, the, the

167:21 phone. The, the what you see that we have and, and

167:31 of the oil and second line what you can see that here and

167:37 actually the old, much greater. , so that in a range

167:44 and then you look at the, at those, those ones and

167:49 the, the, the blue one , and the red is a and

167:55 yellow is the, and the, , the uh actually what you can

168:05 that actually, actually you see the, the here are all the

168:11 contains a much compared to the also including all contains the much lower

168:33 to the original original and uh such increasing the Ame and there is some

168:43 of increasing of unless, unless will outside there that know that how

168:51 how the T SI can significantly alter oil composition. OK. This will

169:01 even more, little bit more. you so much. It, it

169:10 be more complicated what you can see we have a T S R on

169:17 this is the black to black And also we have uh we have

169:23 T S R oil which is the , red point here. And what

169:29 can see that is after the, those are all the this is from

169:39 all these and this is the all, all that. Uh and

169:50 you can see that uh no matter components after T S R, after

169:57 S R and the carbon all become , the the the the remain

170:07 What you can see that that is because the after after the products,

170:16 from organic is of the products of products of the car after P S

170:28 is what kind of form of the , they are coming by Oxide Bridge

170:38 what you can see that what you that is uh just run, you

170:43 , just run your mind that run mass balance a little bit. We

170:49 an original carbon, original oil carbon have much less smaller numbers. And

170:59 reaction after P S R reaction, the carbon ice talks of the oil

171:06 heavier. In other words, there be more carbon enriched in the T

171:15 R or how much product of the . What are your expectation of the

171:23 the carbon light or heavy based on mass balance, think about a little

171:38 the mass balance. So initially it and uh and then you know,

171:46 reaction and then you, you move up to here, you lose

171:50 Yeah, you lose something. So , those, those lost of

171:56 some of them become 02. So carbon I should be. So that

172:02 what? Yeah. Yeah. So come in this, it's about minus

172:15 or something for the, that's But the reason I, I want

172:20 pay that little bit of attention because uh you know, uh I try

172:24 let you, I'm not, not ask you to remember all these things

172:27 you don't need to remember all these . What do you really need to

172:31 this process? This process? So be reduced, oil itself will

172:41 oxidized to and remain the oil to enriched in the 13. So the

172:52 of the CO2 should be in, C 12. Yeah. So that's

172:58 last. So let us look at main controls of the P S.

173:10 that's supposed to question them is to the phone that is uh initially use

173:16 like a hydrogen sulfide or animal sulfide to be existed or required or

173:25 In other words, in other they say, OK, because we

173:28 that the hydrogen sulfide, that is product. Yeah, that's the

173:34 And uh that means if you, you really want to make this kind

173:38 the reaction go and then you need require that you require initial presence of

173:46 hydrogen sulfide. What that means? means if you do have a,

173:51 initially you character a type two S and your products, your products have

173:59 contain a higher hydrogen supply, that of a fact that two could be

174:06 a place is more likely what? then go to the to take

174:12 the go through the S R processes that is true or not, if

174:19 is true. And our prediction to will say, OK, the truth

174:24 be, you will look at top character, type, type, type

174:28 S character developed two. But when look at the, the real

174:34 natural piece that some, some they do not really have a as

174:41 this but still have a significant potential the S R reaction. So that's

174:47 why, why this country. Um thing is about the reactive space.

174:56 a, it's a itself or so actually enough or need something else in

175:05 to initiate this reaction. And uh in mind on it in a,

175:11 a slide which I show the higher the higher the hydrogen sulfide oil versus

175:20 low hydrogen sulfide container oil. It's separation three kilometers, three kilometers.

175:28 cannot, you cannot really, really uh something like uh similar to

175:34 those are things to make a It could be, could be really

175:40 water chemistry. That is why the , that's why we uh real

175:47 This is underwater chemistry. So what , what we really make a very

175:55 contribution to the this scenario is uh our work and we proposed by formation

176:03 chemistry which is uh Megan. So is considered to uh the and the

176:15 . But this is a very very important statement, very, very

176:21 discovery what we made for from our . And uh let us show,

176:28 you here and see that we, run an experiment that we have to

176:35 so and in the presence of watch which which which which can be really

176:46 be reduced by the organic ma you see that see that sodium sodium

176:54 sodium sulfate will be known as very . Yeah, very soluble. The

176:59 of sulf is unlimited even for that this reaction do not. And then

177:08 say, OK, this is the abundant minerals that are in the,

177:19 the action you think of it kind go out there alone. And then

177:33 and we only, we, we make a reaction to that.

177:39 making sausage. So mechanism of you can directly directly reactor with hydrocarbons

177:49 generate the hydrogen sulfide. In other , we make the S R reaction

177:54 . So we answer the first question that in order to make your T

177:58 R reaction go, you don't need really need to initial hydrogen sulfide

178:05 And once you have a right water chemistry and then you can make

178:11 reaction. So this is very important uh observations which remain. And then

178:20 me explain why the why the phage cannot be reduced. So this is

178:28 , this is symmetry of the age the itself that is the like tetra

178:39 . That's the, the, the like me molecules. It's the,

178:44 , the the structurally is very You cannot really, really think this

178:50 , this one. However, the itself is that it increases the concentration

179:02 the sheep to keep them to this . The peak of 995, that's

179:08 , that's the specific peak of the . The go to the bank

179:18 that suggest that the symmetry of the has been charged, which I I

179:27 can I, that's, that's not it work, but the, the

179:34 theory or theory really help us a . So that's uh I just want

179:40 tell, tell you some, some , you know, as your chemist

179:44 do when you, when you use knowledge, when you use your

179:49 you, you, you, I want to bring you here and

179:53 it's actually geology and geochemist use a of the lot of knowledge I have

179:58 use a lot of knowledge of the chemistry. And uh those are

180:03 , those those are just a little of chemistry here, you see that

180:07 are the the structure of the Those are the structure of the

180:16 OK. What you can see that the, you sit in this bun

180:21 length of this bond become, become that suggest that you actually, you

180:29 the symmetry. Actually, you change symmetry of the 4 50. This

180:34 important once you change the symmetry, you change the symmetry of the

180:40 In other words, that means that reaction could have occurring and make this

180:47 in the last seven. So that's , that is the how, how

180:51 know we, we use this technology look at that. And uh one

180:57 the researchers in our group and he the run the initial the the simulation

181:07 reaction simulation and find the find some that that is the that is the

181:14 in interpreted how the ma so itself not to get less stable in the

181:23 of the car. And the, point, the point to what I

181:28 to look at is that what you see that the level of the here

181:40 initially is 1.557 and seven increase. also also the difference difference to different

181:53 of the elements and the the lens different and the, the, the

182:03 graphic symmetry has been destroyed. And we did, we did run

182:16 the, the the the kind of simulation, this is very important

182:25 very important part. And this really, really make, make us

182:31 make us uh give us a very confidence. You know, sometimes when

182:35 do the research, you do your and uh you need to, in

182:40 , when you run some experimental work you need to, you need to

182:46 the right path the right week to determine that that is the the

182:52 direction you want to go. And you pay too much of your efforts

182:58 this is what you and uh because it will take less time, less

183:05 compared to our really experimental work. your reaction? When you look

183:11 you look at them and see that , this is a favorable reactions for

183:22 the for the the the activation look at the activation energy uh the

183:30 to the real and what have what you really fun about. So

183:35 content that I impair energy reactor with oil, that's, that's the reaction

183:44 think six after the show, which very similar to another reaction that five

184:00 that is almost the same kind of damage. It's really encourage us a

184:11 if you, yes and we we could make this reaction good in

184:16 lab and also this kind of activity actually is uh can mix the natural

184:24 that natural. And uh let's have look at the, look at what

184:33 in about the water chemistry formation, chemistry. OK. That's uh

184:39 you see that this temperature actually the and uh there's a different the for

184:49 aqueous calcium storage concentration. That's where line with an increased temperature is actually

184:58 , this concentration is increasing. And another one is uh contact i black

185:11 yellow line. And what we can that and what we can see that

185:17 is actually the condition yes, is . But once you reach the temperature

185:28 the 200 degrees C and the concentration almost zero and the itself concentration condition

185:38 the ice. And also also the, the, the, the

185:44 in the, the condition is high also in the laboratory conditions and also

185:55 . What we see there is another , you can see that this curve

186:03 is the and hydro oxide called the M I H complex was formed because

186:14 one form is actually the Magne in presence of magnes. And the,

186:19 the, the temperature above the 200 C is actually a which is uh

186:27 that the, the, the, you formation water h here to become

186:35 a and we spend about two we do not really know, we

186:42 not really know that because you see if you make the solutions of magnet

186:49 in the, in the room and phd neutron condition, we just do

186:54 have knowledge about the. And so presence and in the nature and

187:01 the the temperature above the 200 degrees and uh form this, this kind

187:08 pre main, the main hydro oxide release is actually this, this kind

187:20 the reactions had been over there in hot water as all the,

187:27 the, the, the, the , ocean, the ocean water studies

187:32 we do the, the, the water, deep Ocean water study.

187:37 over the the already and with increasing the temperature and the the the the

187:45 water become acidic conditions over the back the 19 seventies. But we are

187:53 in that area. We we are an organic geochemistry area. We do

187:58 really have knowledge about knowledge with the with the formation in organic chemistry.

188:07 once we realize that at OK, that our laboratory condition, we simulate

188:13 normally we should be greater than 300 C. But in a regular

188:20 it's uh so and go to go to the, the, the

188:31 labor conditions that the bias of the is actually the rector of the

188:39 So we cannot really, really compare to direct what that is why I

188:46 that this really will help us molecular , really help us do that activity

188:54 the bio and the magnetic. So is the energy react to the reaction

189:01 the oil, it, it have more and more very similar activity.

189:08 that give us the indication that if we, that both the left

189:21 the reaction we can use this as pro to the in the. So

189:34 is that, that is give, to give you ideas, you

189:37 how complicated this process is. And what what we are doing, this

189:46 the kind of thing that what it's really, we spent a few

189:51 and then we got a really good . And what you can see

189:56 this is a reaction path. And I have that this is the back

190:06 actually the reaction of the oil and in the subsurface there should be two

190:13 of reactions. The fourth stage is open prison, this reaction to

190:25 And the because the initial that is the there no initial happiness of other

190:40 . That's, that's it. And once you see here, you have

190:55 some numbers threshold and then this reaction then another reaction picks on actually.

191:07 that's there's two stages of reactions. reaction is so crazy because is reaction

191:19 and the thresholds and the whole reaction . So this is the how this

191:27 the, how the, how the reaction to the our understanding of

191:31 , the the this reaction, the S R reaction system. And then

191:37 did a kinetic studies so that if look at the, this one,

191:42 see that we, we look at different levels, the angles and the

191:49 and that is all the different. . And the included the two additional

192:00 sad which is, yeah, which have a, has a very

192:09 , uh very strong, similar to . And uh interestingly, so reaction

192:37 and, and a condition to get and stronger. It's a really,

192:49 , really at this time, they , and then, then actually the

192:57 depends on the concentration of the sulfate in the lab. And then if

193:04 make corrections of the, of that is how I use the

193:10 to hear that on the, say to the after I correct the

193:18 the correct the concentration correspond to different and the back of each of those

193:26 lines, oh oh I have a . This is this is the

193:32 the benefit. And because the, , the, the, the light

193:38 still above here is not really over . So the, and the,

193:45 they still took the two different positives uh with that, and uh

193:54 we run the, run the kinetics also the, the, we build

194:00 kinetic model and predict the onset of T S R reaction. But this

194:07 the, this is the, look at the, look at the

194:11 model of the and the, what can see that uh those are concentration

194:23 the mechanism in the formation, you higher concentration and then your other will

194:31 to the and then you buy blue. But you can see that

194:41 , the reaction based on I and is the, that's the, you

194:57 , that's the before our work. then there's the many people who did

195:04 kind of work back to 19 19 seventies, even 19 nineties,

195:08 different groups, they do do this of work. And what they,

195:14 , the, the very big issues that they cannot really simulate the T

195:19 reactions for current conditions. The reason reason is that the reason is this

195:28 that all the previous experimental work that about, they either they can,

195:37 initially have a very high hydrogen all animal sulfur presence. And once

195:45 have that condition and so production will very quick as a result. You

195:54 , it's the, the activation energy got is all low lower than the

195:59 kg kilo kilocalories per month. And you do use the to that model

196:06 make a prediction in the subsurface, temperature is a T S R reaction

196:11 happen at 80 degrees C never, can be, never can be to

196:17 , the lower the fat. But nature, obviously, it happens much

196:24 coverage and all the models, all models and they cannot really predict that

196:30 S R can happen, that can happens about at 100 and 40 degrees

196:37 . That's the only model that based what I understand similar really occurring at

196:47 and 40 degrees C in the That's the, that's how, that's

196:53 the, how big the, think , this kind of, uh I

196:58 it's, you know, that, our work and in, in

197:03 in the hydrogen sulfide, the prediction T S R reaction as a benchmark

197:09 uh for the, for the, , the, the sulfide risk prediction

197:15 uh you know, eventually we, generate that we generate the software and

197:21 and then you propose that R predicting , what are we doing there?

197:27 need to think about those. You to think about the, let's think

197:33 the P T condition of the and other. And then you need to

197:41 at the video, look at the information, what I can see

197:46 a chemistry. And uh and from you can see the and uh

198:18 and also, and uh another reaction , no reaction path. Actually,

198:28 call the second, the two stage . This is a thing, the

198:32 thing with R reaction. And that but the, the key point for

198:41 prediction that the, the threshold for average reactions, we need to keep

198:51 as stress. And uh what you see that is uh you have and

198:59 cabinet presentation and uh as a result the T SI you can make a

199:07 of your gas or ratios and the and also the hydrogen sulfide,

199:16 the, the, the. So of the, and uh I think

199:23 is the, this is the kind the things which I added in.

199:27 this this class class material to present only one part of our research

199:36 to this class to the, this . When I review the uh the

199:41 and the I found that on the T S R portion, they

199:46 have one slide about T S And it's actually not really, not

199:52 after the new knowledge, what we in this area. So I think

199:58 uh kind of the things I want see. And we, we made

200:01 really good publications and uh and the , many public in that uh and

200:14 I, I make, I make both of the publications and also also

200:20 think it's uh because of this and think it's uh build our reputations in

200:26 United States. And uh and uh easy for, for, for me

200:31 also my group and uh in a . And we, we got,

200:36 , we have a see that he our boss and uh he has uh

200:44 has the, the research center in and to build a research center that

200:52 2000 0. And I joined his center at 2005 and the US

201:04 And uh last name and, and Jerusalem Israel, he, he has

201:17 wonderful, so fast in the individual and uh water and they, they

201:29 the and join the I AM S airport. I think that uh I

201:50 that's all what I want to share you. Any, any questions.

202:03 , that this is just tell you story that tell you a story and

202:07 that, you know, it's a and they really said that work on

202:15 specific geological geochemistry and geological geological que and uh all natural observations,

202:25 how they they can make this, contributions like the thermo chemical surface

202:32 The key key issues that you need really predict, make something predictable.

202:40 that's the in other words, you need to, you need

202:43 you like like a equation. you need to use that equation to

202:48 a prediction of your generation from. the same thing for the same thing

202:55 the T S R. You need , to understand the mechanisms come up

203:00 uh some kinetics to make a prediction the hydrogen sulfide. That any

203:24 Any questions? Not for this OK. So I think this is

203:32 , this afternoon's work the the the and we talk about the the

203:41 two alteration processes to the oil in reservoir. One is the bad

203:48 which is a low temperature involved in water and the bacteria and uh consumes

203:57 light hydrocarbons. Consumers, the large carbons and Ks and uh eventually resulted

204:17 the heavy oil after the for the after the degradation. So

204:26 this one, this one is that you see that one, that

204:31 more time, it's a lower temperature the water and the bacteria.

204:39 and then I also introduce another, , another alteration process which is uh

204:47 temperature in a mode of water but , not a bacteria. So

204:55 that is that the, that, that is, you know, that

204:59 the so, so, so further reduced and generate the hydrogen. So

205:07 uh CO2 also the auto change, oil quality oil quality is uh as

205:14 said to, to show this here uh it's uh this increase of the

205:21 of the T S R reaction is more saturates and uh aromatics is to

205:36 more aromatics. And also there's some geochemical characteristics. You can use that

205:47 identify them, identify the extent of T SI reactions in your order.

205:56 uh I introduced some uh some key mechanisms so that 22 stage reactions

206:05 the of the thermo chemical reduction, think this is a, this is

206:11 of the key, one of the key observations what we met at.

206:16 the, that's the the reaction can this reaction coming slowly but now and

206:31 the threshold and then the catalog reaction and the whole reaction will occur.

206:40 that's back to back to this And then maybe you have a,

206:45 have a, could there be home understanding why the concentration of so bad

206:55 ? It's much higher than here. uh this portion is much lower.

207:01 that could be to see that, that this area also have high hydrogen

207:08 that could be to the really locally water chemistry that as we know that

207:16 chemistry is so the Sufi Maan can and the main content I pair concentration

207:24 is real, real space in the . So maybe maybe the action that

207:33 need to, you definitely need to that one in and then you,

207:37 get a better understanding how, how watch a chemistry change in your information

207:43 uh that maybe produce, produce, a better prediction. This area

207:51 maybe that's somehow your your reaction reach in the first stage of the reaction

207:59 not really accumulate the enough hydrogen sulfide kick off the hydrogen sulfide, take

208:06 lot of action and then go here you kick off to kick off the

208:12 sofa and the catalog of reactions. once we have, once, once

208:18 have technology and could get a better of the this special distribution, this

208:26 about hybrid sour. OK. Stop .

-
+